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Issue 35, 2005
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Synthesis of bi- and tricyclic arylboronates via Cp*RuCl-catalyzed cycloaddition of α,ω-diynes with ethynylboronate

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Abstract

In the presence of 5–10 mol% Cp*RuCl(cod), 1,6- and 1,7-diynes were allowed to react with an ethynylboronate at ambient temperature to give rise to bi- and tricyclic arylboronates in 64–93% isolated yields.

Graphical abstract: Synthesis of bi- and tricyclic arylboronates via Cp*RuCl-catalyzed cycloaddition of α,ω-diynes with ethynylboronate

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Publication details

The article was received on 17 May 2005, accepted on 13 Jul 2005 and first published on 05 Aug 2005


Article type: Communication
DOI: 10.1039/B506977G
Citation: Chem. Commun., 2005, 4438-4440
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    Synthesis of bi- and tricyclic arylboronates via Cp*RuCl-catalyzed cycloaddition of α,ω-diynes with ethynylboronate

    Y. Yamamoto, K. Hattori, J. Ishii, H. Nishiyama and K. Itoh, Chem. Commun., 2005, 4438
    DOI: 10.1039/B506977G

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