Issue 33, 2005
From the journal:

Chemical Communications

Allosteric pitch length tuning of a dinuclear double helicate

Christian J. Baylies,a   John C. Jeffery,b   Tom A. Miller,b   Ryan Moon,a   Craig R. Rice*a  and  T. Riis-Johannessenb  

* Corresponding authors

a Department of Chemical and Biological Sciences, University of Huddersfield, Huddersfield, UK
E-mail: c.r.rice@hud.ac.uk
Fax: (+44)148-447-2182
Tel: (+44)148-447-3759

b School of Chemistry, University of Bristol, Cantocks Close, Bristol, UK

Abstract

Self assembly of the ditopic ligand L1 with Cu2+ gives the dinuclear double helicate [Cu2(L1)2]4+, which can further coordinate s-block cations. This coordination alters the helicate pitch to a variety of different lengths depending on the size and charge of the guest cation.

Graphical abstract: Allosteric pitch length tuning of a dinuclear double helicate

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Article information

DOI
https://doi.org/10.1039/B506199G
Article type
Communication
Submitted
03 May 2005
Accepted
27 Jun 2005
First published
21 Jul 2005

Chem. Commun., 2005, 4158-4160

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Allosteric pitch length tuning of a dinuclear double helicate

C. J. Baylies, J. C. Jeffery, T. A. Miller, R. Moon, C. R. Rice and T. Riis-Johannessen, Chem. Commun., 2005, 4158 DOI: 10.1039/B506199G

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