Issue 20, 2005
From the journal:

Chemical Communications

Hindered rotation in an “exploded” biphenyl†

Ognjen Š. Miljanić,a   Sangdon Han,‡a   Daniel Holmes,a   Gaston R. Schallera  and  K. Peter C. Vollhardt*a  

* Corresponding authors

a Center for New Directions in Organic Synthesis, Department of Chemistry, University of California at Berkeley, and the Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, USA
E-mail: kpcv@berkeley.edu
Fax: +1 510 643 5208
Tel: +1 510 642 0286

Abstract

The first cases of hindered rotation around the triple bond in simple diphenylacetylenes were observed, including that in chiral 2,2′-bis(trimethylsilyl)-6,6′-bis(dimethylthexylsilyl)diphenylacetylene.

Graphical abstract: Hindered rotation in an “exploded” biphenyl

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Article information

DOI
https://doi.org/10.1039/B503173G
Article type
Communication
Submitted
03 Mar 2005
Accepted
21 Mar 2005
First published
06 Apr 2005

Chem. Commun., 2005, 2606-2608

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Hindered rotation in an “exploded” biphenyl

O. Š. Miljanić, S. Han, D. Holmes, G. R. Schaller and K. P. C. Vollhardt, Chem. Commun., 2005, 2606 DOI: 10.1039/B503173G

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