Issue 21, 2005

Synthesis of novel palladium OCN-pincer complexes: unprecedented sequential C(sp3)–H activation and aerobic oxidation in the reaction of N,N-dialkyl-3-[(N,N-dimethylamino)methyl]-2-iodoanilines with Pd2(dba)3

Abstract

The reaction of N,N-dialkyl-3-[(N,N-dimethylamino)methyl]-2-iodoanilines with Pd2(dba)3 under O2 gives palladium OCN-pincer complexes by means of an unprecedented process that involves the formal aerobic oxidation of C(sp3)–H bonds at the α position of the aniline N atom.

Graphical abstract: Synthesis of novel palladium OCN-pincer complexes: unprecedented sequential C(sp3)–H activation and aerobic oxidation in the reaction of N,N-dialkyl-3-[(N,N-dimethylamino)methyl]-2-iodoanilines with Pd2(dba)3

Supplementary files

Article information

Article type
Communication
Submitted
25 Feb 2005
Accepted
07 Apr 2005
First published
15 Apr 2005

Chem. Commun., 2005, 2738-2740

Synthesis of novel palladium OCN-pincer complexes: unprecedented sequential C(sp3)–H activation and aerobic oxidation in the reaction of N,N-dialkyl-3-[(N,N-dimethylamino)methyl]-2-iodoanilines with Pd2(dba)3

D. Solé, L. Vallverdú, X. Solans and M. Font-Bardia, Chem. Commun., 2005, 2738 DOI: 10.1039/B502854J

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