Issue 24, 2005

Condensed metallaborane clusters: synthesis and structure of Fe2(CO)65-C5Me5RuCO)(η5-C5Me5Ru)B6H10

Abstract

Mild pyrolysis of (η5-C5Me5Ru)2B6H12 with Fe2(CO)9 yields the 12 skeletal electron pair (sep) Fe2(CO)65-C5Me5RuCO)(η5-C5Me5Ru)B6H10 cluster; the title compound represents a novel class of hybrid multiple cluster in which a Fe2B2 tetrahedron has been fused to a ruthenaborane substrate.

Graphical abstract: Condensed metallaborane clusters: synthesis and structure of Fe2(CO)6(η5-C5Me5RuCO)(η5-C5Me5Ru)B6H10

Supplementary files

Article information

Article type
Communication
Submitted
18 Feb 2005
Accepted
06 Apr 2005
First published
11 May 2005

Chem. Commun., 2005, 3080-3082

Condensed metallaborane clusters: synthesis and structure of Fe2(CO)65-C5Me5RuCO)(η5-C5Me5Ru)B6H10

S. Ghosh, T. P. Fehlner and B. C. Noll, Chem. Commun., 2005, 3080 DOI: 10.1039/B502559A

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