Issue 22, 2005
From the journal:

Chemical Communications

Organic phase stabilization of rhodium nanoparticlecatalyst by direct phase transfer from aqueous solution to room temperature ionic liquid based on surfactant counter anion exchange†

Vincent Mévellec,a   Bastien Leger,a   Marc Mauduita  and  Alain Roucoux*a  

* Corresponding authors

a UMR CNRS 6052 “Synthèses et Activations de Biomolécules”, Ecole Nationale Supérieure de Chimie de Rennes, Institut de Chimie de Rennes, Avenue du Général Leclerc, Rennes, France
E-mail: alain.Roucoux@ensc-rennes.fr
Fax: (33) (0)223 238 199

Abstract

We describe the organic phase transfer of surfactant-stabilized rhodium nanoparticles previously synthesized in an aqueous solution of N,N-dimethyl-N-dodecyl-N-(2-hydroxyethyl)ammonium chloride (HEA12Cl); the addition of LiN(Tf)2 to the aqueous suspension of Rh–HEA12Cl transferred the hydrosol nanoparticles to an ionic liquid phase.

Graphical abstract: Organic phase stabilization of rhodium nanoparticle catalyst by direct phase transfer from aqueous solution to room temperature ionic liquid based on surfactant counter anion exchange

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Article information

DOI
https://doi.org/10.1039/B502169N
Article type
Communication
Submitted
10 Feb 2005
Accepted
07 Apr 2005
First published
21 Apr 2005

Chem. Commun., 2005, 2838-2839

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Organic phase stabilization of rhodium nanoparticle catalyst by direct phase transfer from aqueous solution to room temperature ionic liquid based on surfactant counter anion exchange

V. Mévellec, B. Leger, M. Mauduit and A. Roucoux, Chem. Commun., 2005, 2838 DOI: 10.1039/B502169N

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