Issue 22, 2005

Two-dimensional organization of [ZnGe3S9(H2O)]4− supertetrahedral clusters templated by a metal complex

Abstract

Under the structure-directing effect of a metal complex formed in situ, supertetrahedral [ZnGe3S6(H2O)(S3)1/2]1− clusters alternate with tetrahedral Zn(H2O)(S3)1/21− units to form a two-dimensional wide bandgap semiconductor that shows photocatalytic activity for H2 production from aqueous solution.

Graphical abstract: Two-dimensional organization of [ZnGe3S9(H2O)]4− supertetrahedral clusters templated by a metal complex

Article information

Article type
Communication
Submitted
08 Feb 2005
Accepted
11 Apr 2005
First published
22 Apr 2005

Chem. Commun., 2005, 2805-2807

Two-dimensional organization of [ZnGe3S9(H2O)]4− supertetrahedral clusters templated by a metal complex

N. Zheng, X. Bu and P. Feng, Chem. Commun., 2005, 2805 DOI: 10.1039/B501775K

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