Issue 15, 2005
From the journal:

Chemical Communications

Reactivity of a 1∶1 copper–oxygen complex: isolation of a Cu(ii)-o-iminosemiquinonato species†

Anne M. Reynolds,a   Elizabeth A. Lewis,a   Nermeen W. Aboelellaa  and  William B. Tolman*a  

* Corresponding authors

a Department of Chemistry and Center for Metals in Biocatalysis, University of Minnesota, 207 Pleasant Street, SE, Minneapolis, MN, USA
E-mail: tolman@chem.umn.edu
Fax: 612-624-7029
Tel: 612-625-4061

Abstract

While a 1∶1 Cu–O2 adduct is generally unreactive with organic substrates, phosphines displace O2via an associative process and added Cu(I) leads to a novel internal ligand oxidation to yield a Cu(II)-o-iminosemiquinone complex.

Graphical abstract: Reactivity of a 1∶1 copper–oxygen complex: isolation of a Cu(ii)-o-iminosemiquinonato species

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Article information

DOI
https://doi.org/10.1039/B418939F
Article type
Communication
Submitted
17 Dec 2004
Accepted
11 Feb 2005
First published
24 Feb 2005

Chem. Commun., 2005, 2014-2016

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Reactivity of a 1∶1 copper–oxygen complex: isolation of a Cu(II)-o-iminosemiquinonato species

A. M. Reynolds, E. A. Lewis, N. W. Aboelella and W. B. Tolman, Chem. Commun., 2005, 2014 DOI: 10.1039/B418939F

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