Issue 10, 2005
From the journal:

Chemical Communications

Evidence for the first oxidative insertion of a transition metal into a digallane(4): synthesis, structural characterisation and EPR studies of [Cp2ZrIII{Ga[N(Ar)C(H)]2}2][Li(THF)4], Ar = C6H3Pri2-2,6

Robert J. Baker,a   Cameron Jones*a  and  Damien M. Murphya  

* Corresponding authors

a Centre for Fundamental and Applied Main Group Chemistry, School of Chemistry, Cardiff University, Cardiff, P.O. Box 912, Park Place, Cardiff, UK

Abstract

Treatment of “ZrCp2” with the digallane(4), [{Ga[N(Ar)C(H)]2}2], Ar = C6H3Pri2-2,6, in the presence of excess BunLi leads to the first example of a gallyl–Group 4 complex, [Cp2Zr{Ga[N(Ar)C(H)]2}2][Li(THF)4], via an unprecedented oxidative insertion reaction; the paramagnetic complex has been characterised by X-ray crystallography and EPR spectroscopy.

Graphical abstract: Evidence for the first oxidative insertion of a transition metal into a digallane(4): synthesis, structural characterisation and EPR studies of [Cp2ZrIII{Ga[N(Ar)C(H)]2}2][Li(THF)4], Ar = C6H3Pri2-2,6

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B417720G
Article type
Communication
Submitted
25 Nov 2004
Accepted
23 Dec 2004
First published
19 Jan 2005

Chem. Commun., 2005, 1339-1341

Permissions

Request permissions

Evidence for the first oxidative insertion of a transition metal into a digallane(4): synthesis, structural characterisation and EPR studies of [Cp2ZrIII{Ga[N(Ar)C(H)]2}2][Li(THF)4], Ar = C6H3Pri2-2,6

R. J. Baker, C. Jones and D. M. Murphy, Chem. Commun., 2005, 1339 DOI: 10.1039/B417720G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements