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Issue 9, 2005
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Enhanced reactivity in OH/NH/π polyfunctional systems through coupled proton/electron transfer in the excited state: the photocyclisation of 2-allyl-3-aminophenol

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Abstract

The photocyclisation rate of 2-allyl-3-(or 5-)aminophenols (1, 4 and 8) is dramatically enhanced, when compared with reference compounds, as a consequence of a coupled proton/electron transfer process.

Graphical abstract: Enhanced reactivity in OH/NH/π polyfunctional systems through coupled proton/electron transfer in the excited state: the photocyclisation of 2-allyl-3-aminophenol

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Publication details

The article was received on 01 Nov 2004, accepted on 15 Dec 2004 and first published on 18 Jan 2005


Article type: Communication
DOI: 10.1039/B416625F
Citation: Chem. Commun., 2005, 1203-1205
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    Enhanced reactivity in OH/NH/π polyfunctional systems through coupled proton/electron transfer in the excited state: the photocyclisation of 2-allyl-3-aminophenol

    E. A. Leo, R. Tormos and M. A. Miranda, Chem. Commun., 2005, 1203
    DOI: 10.1039/B416625F

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