Issue 9, 2005
From the journal:

Chemical Communications

Enhanced reactivity in OH/NH/π polyfunctional systems through coupled proton/electron transfer in the excited state: the photocyclisation of 2-allyl-3-aminophenol

Edgar A. Leo,a   Rosa Tormosa  and  Miguel A. Miranda*a  

* Corresponding authors

a Departamento de Química-ITQ UPV-CSIC, Universidad Politécnica de Valencia, Camino de Vera, s/n, Valencia, Spain
E-mail: mmiranda@qim.upv.es
Fax: +34 963879349
Tel: +34 963877807

Abstract

The photocyclisation rate of 2-allyl-3-(or 5-)aminophenols (1, 4 and 8) is dramatically enhanced, when compared with reference compounds, as a consequence of a coupled proton/electron transfer process.

Graphical abstract: Enhanced reactivity in OH/NH/π polyfunctional systems through coupled proton/electron transfer in the excited state: the photocyclisation of 2-allyl-3-aminophenol

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Article information

DOI
https://doi.org/10.1039/B416625F
Article type
Communication
Submitted
01 Nov 2004
Accepted
15 Dec 2004
First published
18 Jan 2005

Chem. Commun., 2005, 1203-1205

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Enhanced reactivity in OH/NH/π polyfunctional systems through coupled proton/electron transfer in the excited state: the photocyclisation of 2-allyl-3-aminophenol

E. A. Leo, R. Tormos and M. A. Miranda, Chem. Commun., 2005, 1203 DOI: 10.1039/B416625F

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