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Issue 7, 2005
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A general method for making bicyclic compounds with nitrogen at a bridgehead—application to the halichlorine spiro subunit

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Abstract

N-Protected β-amino aldehydes having the nitrogen in a ring are easily converted into Morita–Baylis–Hillman adducts; O-acetylation and N-deprotection result in spontaneous cyclization to bicyclic structures having nitrogen at a bridgehead.

Graphical abstract: A general method for making bicyclic compounds with nitrogen at a bridgehead—application to the halichlorine spiro subunit

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Publication details

The article was received on 26 Aug 2004, accepted on 07 Oct 2004 and first published on 23 Dec 2004


Article type: Communication
DOI: 10.1039/B413481H
Citation: Chem. Commun., 2005, 906-908
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    A general method for making bicyclic compounds with nitrogen at a bridgehead—application to the halichlorine spiro subunit

    D. L. J. Clive, M. Yu and Z. Li, Chem. Commun., 2005, 906
    DOI: 10.1039/B413481H

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