Issue 1, 2005
From the journal:

Chemical Communications

[H3N(CH2)7NH3]8(CH3NH3)2Sn(iv)Sn(ii)12I46 – a mixed-valent hybrid compound with a uniquely templated defect-perovskite structure†‡

Jun Guan,a   Zhongjia Tanga  and  Arnold M. Guloy*a  

* Corresponding authors

a Department of Chemistry and the Center for Materials Chemistry, University of Houston, Houston, USA
E-mail: aguloy@uh.edu

Abstract

The incorporation of H3N(CH2)7NH3 with CH3NH3SnI3 resulted in the formation of a mixed-valent and semiconducting (Eg = 0.84 eV) organic-based perovskite, [H3N(CH2)7NH3]8(CH3NH3)2Sn(IV)Sn(II)12I46, with a unique 3D defect-perovskite structure with ordered vacancies at the Sn and I sites.

Graphical abstract: [H3N(CH2)7NH3]8(CH3NH3)2Sn(iv)Sn(ii)12I46 – a mixed-valent hybrid compound with a uniquely templated defect-perovskite structure

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Article information

DOI
https://doi.org/10.1039/B411322E
Article type
Communication
Submitted
26 Jul 2004
Accepted
30 Sep 2004
First published
19 Nov 2004

Chem. Commun., 2005, 48-50

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[H3N(CH2)7NH3]8(CH3NH3)2Sn(IV)Sn(II)12I46 – a mixed-valent hybrid compound with a uniquely templated defect-perovskite structure

J. Guan, Z. Tang and A. M. Guloy, Chem. Commun., 2005, 48 DOI: 10.1039/B411322E

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