Issue 24, 2004
From the journal:

Chemical Communications

Formation of a chiral NPPN ligandviametallation of acyclic NPNCN systems

Tristram Chivers,*a   May C. Copseya  and  Masood Parveza  

* Corresponding authors

a Department of Chemistry, University of Calgary, Calgary, Canada T2N 1N4
E-mail: chivers@ucalgary.ca
Fax: +1 (403) 289-9488
Tel: +1 (403) 220-5741

Abstract

A new type of bidentate N,N′-chelating ligand containing a chiral phosphorus centre has been synthesized via the metallation of an acyclic NPNCN species. The zwitterionic ligand backbone contains a phosphenium centre stabilised by an imido phosphine fragment.

Graphical abstract: Formation of a chiral NPPN ligand via metallation of acyclic NPNCN systems

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Article information

DOI
https://doi.org/10.1039/B413137A
Article type
Communication
Submitted
26 Aug 2004
Accepted
20 Sep 2004
First published
09 Nov 2004

Chem. Commun., 2004, 2818-2819

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Formation of a chiral NPPN ligand via metallation of acyclic NPNCN systems

T. Chivers, M. C. Copsey and M. Parvez, Chem. Commun., 2004, 2818 DOI: 10.1039/B413137A

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