Issue 23, 2004
From the journal:

Chemical Communications

Mechanism of hydrogen transfer to imines from a hydroxycyclopentadienyl ruthenium hydride. Support for a stepwise mechanism†

Joseph S. M. Samec,a   Alida H. Élla  and  Jan-E. Bäckvall*a  

* Corresponding authors

a Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, SE-106 91 Stockholm, Sweden
E-mail: jeb@organ.su.se
Fax: +46-8-154908
Tel: +46-8-674 7178

Abstract

The negligible double kinetic deuterium isotope effect (kHH/kDD = 1.05) in the reaction where [2,3,4,5-Ph4(η5-C4COH)Ru(CO)2H (2) transfers a hydride and a proton to N-phenyl-[1-(4-methoxyphenyl)ethylidene]amine (4) indicates that no bond to hydrogen is broken or formed in the rate-determining step.

Graphical abstract: Mechanism of hydrogen transfer to imines from a hydroxycyclopentadienyl ruthenium hydride. Support for a stepwise mechanism

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Article information

DOI
https://doi.org/10.1039/B410698A
Article type
Communication
Submitted
17 Jul 2004
Accepted
09 Sep 2004
First published
06 Oct 2004

Chem. Commun., 2004, 2748-2749

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Mechanism of hydrogen transfer to imines from a hydroxycyclopentadienyl ruthenium hydride. Support for a stepwise mechanism

J. S. M. Samec, A. H. Éll and Jan-E. Bäckvall, Chem. Commun., 2004, 2748 DOI: 10.1039/B410698A

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