Issue 22, 2004
From the journal:

Chemical Communications

Capturing a metastable chiral polymorph of an achiral molecule—hexa-O-benzoyl-myo-inositol†

Rajesh G. Gonnade,a   Mohan M. Bhadbhade*a  and  Mysore S. Shashidhar*b  

* Corresponding authors

a Center for Materials Characterization, National Chemical Laboratory, Dr. Homi Bhabha Road, Pashan, Pune, India
E-mail: mohanb@sil.ncl.res.in
Fax: +91-20-25893355
Tel: +91-20-25893300

b Division of Organic Synthesis, National Chemical Laboratory, Dr. Homi Bhabha Road, Pashan, Pune, India

Abstract

myo-Inositol hexabenzoate having meso configuration produces chiral polymorph (form I) when crystallized rapidly but yields achiral polymorph (form II) when allowed to crystallize slowly; in the mother liquor form I slowly but completely disappears to give form II.

Graphical abstract: Capturing a metastable chiral polymorph of an achiral molecule—hexa-O-benzoyl-myo-inositol

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Article information

DOI
https://doi.org/10.1039/B410051D
Article type
Communication
Submitted
02 Jul 2004
Accepted
17 Aug 2004
First published
27 Sep 2004

Chem. Commun., 2004, 2530-2531

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Capturing a metastable chiral polymorph of an achiral molecule—hexa-O-benzoyl-myo-inositol

R. G. Gonnade, M. M. Bhadbhade and M. S. Shashidhar, Chem. Commun., 2004, 2530 DOI: 10.1039/B410051D

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