Issue 19, 2004
From the journal:

Chemical Communications

New Pb–Pb bonds: syntheses and molecular structures of hexabiphenyldiplumbane and tri(trisbiphenylplumbyl)plumbate

Yuzhong Wang,a   Brandon Quillian,a   Pingrong Wei,a   Xiao-Juan Yanga  and  Gregory H. Robinson*a  

* Corresponding authors

a Department of Chemistry, The University of Georgia, Athens, Georgia, USA
E-mail: robinson@chem.uga.edu

Abstract

Reaction of lead(II) chloride with biphenylmagnesium bromide yields Bp3Pb–PbBp3 and [(THF)3Mg(μ-Cl)3Mg(THF)3][Pb(PbBp3)3] (Bp = biphenyl), which, upon single crystal X-ray crystallographic analysis, reveals an interesting variation of Pb–Pb bond distances.

Graphical abstract: New Pb–Pb bonds: syntheses and molecular structures of hexabiphenyldiplumbane and tri(trisbiphenylplumbyl)plumbate

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B408860N
Article type
Communication
Submitted
03 Jun 2004
Accepted
13 Jul 2004
First published
20 Aug 2004

Chem. Commun., 2004, 2224-2225

Permissions

Request permissions

New Pb–Pb bonds: syntheses and molecular structures of hexabiphenyldiplumbane and tri(trisbiphenylplumbyl)plumbate

Y. Wang, B. Quillian, P. Wei, X. Yang and G. H. Robinson, Chem. Commun., 2004, 2224 DOI: 10.1039/B408860N

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements