Issue 17, 2004
From the journal:

Chemical Communications

(Bu3Sn)2–TBAF: a new combination reagent for the reduction and deuteration of aryl bromides and iodides†

David C. Harrowven,*a   Ian L. Guya  and  Michael I. T. Nunna  

* Corresponding authors

a Department of Chemistry, University of Southampton, Southampton, UK
E-mail: dch2@soton.ac.uk

Abstract

The combination of (Bu3Sn)2 and TBAF has been shown to reduce aromatic bromides and iodides in excellent yields under mild conditions. When the residual water in TBAF is exchanged for D2O, the halogen is replaced by a deuterium atom.

Graphical abstract: (Bu3Sn)2–TBAF: a new combination reagent for the reduction and deuteration of aryl bromides and iodides

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Article information

DOI
https://doi.org/10.1039/B406103A
Article type
Communication
Submitted
23 Apr 2004
Accepted
26 May 2004
First published
12 Jul 2004

Chem. Commun., 2004, 1966-1967

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(Bu3Sn)2–TBAF: a new combination reagent for the reduction and deuteration of aryl bromides and iodides

D. C. Harrowven, I. L. Guy and M. I. T. Nunn, Chem. Commun., 2004, 1966 DOI: 10.1039/B406103A

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