The three-electron heteropoly blue [P6Mo18O73]11− with a basket-shaped skeleton

Xian-Ming Zhang; Hai-Shun Wu; Fu-Qiang Zhang; Alexander Prikhod'ko; Shigemasa Kuwata; Peter Comba

doi:10.1039/B405931J

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The three-electron heteropoly blue [P₆Mo₁₈O₇₃]¹¹⁻ with a basket-shaped skeleton†

Xian-Ming Zhang,*^ab Hai-Shun Wu,^a Fu-Qiang Zhang,^a Alexander Prikhod'ko,^b Shigemasa Kuwata^b and Peter Comba*^b

Author affiliations

* Corresponding authors

^a School of Chemistry & Material Science, Shanxi Normal University, Shanxi, Linfen 041004, P. R. China
E-mail: zhangxm@dns.sxtu.edu.cn

^b Anorganisch-Chemisches Institut, Universität Heidelberg, Im Neuenheimer Feld 270, D-69120 Heidelberg, Germany
E-mail: peter.comba@aci.uni-heidelberg.de

Abstract

The novel basket-shaped three-electron-reduced heteropoly blue [H₂dmpip]₅[K ⊂ P₆Mo₁₈O₇₃] was prepared and characterized; it shows reversible one-electron redox properties.

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Article information

DOI: https://doi.org/10.1039/B405931J
Article type: Communication
Submitted: 20 Apr 2004
Accepted: 01 Jul 2004
First published: 13 Aug 2004

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Chem. Commun., 2004, 2046-2047

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The three-electron heteropoly blue [P₆Mo₁₈O₇₃]¹¹⁻ with a basket-shaped skeleton

X. Zhang, H. Wu, F. Zhang, A. Prikhod'ko, S. Kuwata and P. Comba, Chem. Commun., 2004, 2046 DOI: 10.1039/B405931J

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Chemical Communications