Issue 14, 2004
From the journal:

Chemical Communications

Iridium-catalyzed coupling of simple primary or secondary amines, aldehydes and trimethylsilylacetylene: preparation of propargylic amines

Satoshi Sakaguchi,a   Tomoya Mizuta,a   Masuyuki Furuwan,a   Takashi Kuboa  and  Yasutaka Ishii*a  

* Corresponding authors

a Department of Applied Chemistry, Faculty of Engineering & High Technology Research Center, Kansai University, Suita, Osaka 564-8680, Japan
E-mail: ishii@ipcku.kansai-u.ac.jp

Abstract

The coupling of amines, aldehydes and trimethylsilylacetylene was found to be promoted in the presence of a catalytic amount of [IrCl(cod)]2; 1 : 1 : 1 or 1 : 2 : 2 coupling products were obtained by allowing primary amine to react with aldehyde and trimethylsilylacetylene.

Graphical abstract: Iridium-catalyzed coupling of simple primary or secondary amines, aldehydes and trimethylsilylacetylene: preparation of propargylic amines

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Article information

DOI
https://doi.org/10.1039/B404430D
Article type
Communication
Submitted
23 Mar 2004
Accepted
14 May 2004
First published
08 Jun 2004

Chem. Commun., 2004, 1638-1639

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Iridium-catalyzed coupling of simple primary or secondary amines, aldehydes and trimethylsilylacetylene: preparation of propargylic amines

S. Sakaguchi, T. Mizuta, M. Furuwan, T. Kubo and Y. Ishii, Chem. Commun., 2004, 1638 DOI: 10.1039/B404430D

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