Issue 12, 2004
From the journal:

Chemical Communications

Palladium catalyzed amination of vinyl chlorides: a new entry to imines, enamines and 2-amino-1,3-butadienes

José Barluenga,*a   M. Alejandro Fernández,a   Fernando Aznara  and  Carlos Valdésa  

* Corresponding authors

a Instituto Universitario de Química Organometálica “Enrique Moles”, Universidad de Oviedo, Oviedo, 33071, Spain
E-mail: Barluenga@uniovi.es
Fax: 34 985103450
Tel: 34 985103450

Abstract

Vinyl chlorides are employed for the first time in palladium catalyzed cross-coupling reactions with amines to furnish imines and enamines. The new methodology has been applied to the synthesis of 2-amino-1,3-butadienes, that could not be achieved from the corresponding bromides.

Graphical abstract: Palladium catalyzed amination of vinyl chlorides: a new entry to imines, enamines and 2-amino-1,3-butadienes

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Article information

DOI
https://doi.org/10.1039/B403655G
Article type
Communication
Submitted
10 Mar 2004
Accepted
08 Apr 2004
First published
14 May 2004

Chem. Commun., 2004, 1400-1401

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Palladium catalyzed amination of vinyl chlorides: a new entry to imines, enamines and 2-amino-1,3-butadienes

J. Barluenga, M. A. Fernández, F. Aznar and C. Valdés, Chem. Commun., 2004, 1400 DOI: 10.1039/B403655G

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