Issue 14, 2004
From the journal:

Chemical Communications

On the importance of steady-state isotopic techniques for the investigation of the mechanism of the reverse water-gas-shift reaction†

Daniele Tibiletti,a   Alexandre Goguet,a   Frederic C. Meunier,*a   John P. Breena  and  Robbie Burcha  

* Corresponding authors

a CenTACat, School of Chemistry, Queen's University Belfast, Belfast, Northern Ireland
E-mail: f.meunier@qub.ac.uk
Fax: +44 28 9097 2117
Tel: +44 28 90974420

Abstract

The formation and reactivity of surface intermediates in the reverse water-gas-shift reaction on a Pt/CeO2 catalyst are critically dependent on the reaction conditions so that conclusions regarding the reaction mechanism cannot be inferred using ex operando conditions.

Graphical abstract: On the importance of steady-state isotopic techniques for the investigation of the mechanism of the reverse water-gas-shift reaction

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Article information

DOI
https://doi.org/10.1039/B403438D
Article type
Communication
Submitted
05 Mar 2004
Accepted
14 May 2004
First published
08 Jun 2004

Chem. Commun., 2004, 1636-1637

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On the importance of steady-state isotopic techniques for the investigation of the mechanism of the reverse water-gas-shift reaction

D. Tibiletti, A. Goguet, F. C. Meunier, J. P. Breen and R. Burch, Chem. Commun., 2004, 1636 DOI: 10.1039/B403438D

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