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Issue 14, 2004
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On the importance of steady-state isotopic techniques for the investigation of the mechanism of the reverse water-gas-shift reaction

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Abstract

The formation and reactivity of surface intermediates in the reverse water-gas-shift reaction on a Pt/CeO2 catalyst are critically dependent on the reaction conditions so that conclusions regarding the reaction mechanism cannot be inferred using ex operando conditions.

Graphical abstract: On the importance of steady-state isotopic techniques for the investigation of the mechanism of the reverse water-gas-shift reaction

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Publication details

The article was received on 05 Mar 2004, accepted on 14 May 2004 and first published on 08 Jun 2004


Article type: Communication
DOI: 10.1039/B403438D
Citation: Chem. Commun., 2004, 1636-1637
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    On the importance of steady-state isotopic techniques for the investigation of the mechanism of the reverse water-gas-shift reaction

    D. Tibiletti, A. Goguet, F. C. Meunier, J. P. Breen and R. Burch, Chem. Commun., 2004, 1636
    DOI: 10.1039/B403438D

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