Supramolecular assembly of ligand-directed triangular {CuII3Cl} clusters with spin frustration and spin-chain behaviour

Georg Seeber; Paul Kögerler; Benson M. Kariuki; Leroy Cronin

doi:10.1039/B402487G

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Supramolecular assembly of ligand-directed triangular {Cu^II₃Cl} clusters with spin frustration and spin-chain behaviour†

Georg Seeber,^a Paul Kögerler,^b Benson M. Kariuki^c and Leroy Cronin*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, University of Glasgow, Glasgow, UK
E-mail: L.Cronin@chem.gla.ac.uk

^b Ames Laboratory and Department of Physics & Astronomy, Iowa State University, Ames, IA 50011, USA

^c School of Chemistry, University of Birmingham, Edgbaston, Birmingham, UK

Abstract

Triangular {Cu^II₃Cl} clusters, containing a chloro ligand in an unprecedented trigonal planar coordination mode, are assembled in a 3-D array by the combination of coordinative and hydrogen-bonded interactions, which result in magnetically isolated 1-D chains exhibiting a combination of spin frustration and spin-chain behaviour.

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Article information

DOI: https://doi.org/10.1039/B402487G
Article type: Communication
Submitted: 18 Feb 2004
Accepted: 19 May 2004
First published: 11 Jun 2004

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Chem. Commun., 2004, 1580-1581

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Supramolecular assembly of ligand-directed triangular {Cu^II₃Cl} clusters with spin frustration and spin-chain behaviour

G. Seeber, P. Kögerler, B. M. Kariuki and L. Cronin, Chem. Commun., 2004, 1580 DOI: 10.1039/B402487G

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