Issue 9, 2004
From the journal:

Chemical Communications

Ferromagnetic NiII–GdIII interactions in complexes with NiGd, NiGdNi, and NiGdGdNi cores supported by tripodal ligands†

Tomoka Yamaguchi,a   Yukinari Sunatsuki,a   Masaaki Kojima,*a   Haruo Akashi,b   Masanobu Tsuchimoto,c   Nazzareno Re,d   Shutaro Osae  and  Naohide Matsumotoe  

* Corresponding authors

a Department of Chemistry, Faculty of Science, Okayama University, Tsushima-naka 3-1-1, Okayama 700-8530, Japan
E-mail: kojima@cc.okayama-u.ac.jp
Fax: +81-86-251-7842

b Research Institute of Natural Sciences, Okayama University of Science, Okayama 700-0005, Japan

c Department of Life and Environmental Sciences, Chiba Institute of Technology, Chiba 275-0023, Japan

d Facoltà di Farmacia, Università degli Studi “G. D'Annunzio”, I-66100 Chieti, Italy

e Department of Chemistry, Faculty of Science, Kumamoto University, Kumamoto 860-8555, Japan

Abstract

Dinuclear [(NiL)Gd(hfac)2(EtOH)] (H3L = 1,1,1-tris(N-salicylideneaminomethyl)ethane, Hhfac = hexafluoroacetylacetone), trinuclear [(NiL)2Gd(NO3)], and tetranuclear [(NiL)Gd(CH3CO2)2(MeOH)]2 complexes, were prepared by treating [Ni(HL)] with [Gd(hfac)3(H2O)2], Gd(NO3)3·6H2O, and Gd(CH3CO2)3·4H2O, respectively, in the presence of Et3N. All the complexes show that ferromagnetic interactions occur between the NiII and GdIII ions.

Graphical abstract: Ferromagnetic NiII–GdIII interactions in complexes with NiGd, NiGdNi, and NiGdGdNi cores supported by tripodal ligands

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Supplementary files

Article information

DOI
https://doi.org/10.1039/B401033G
Article type
Communication
Submitted
01 Jan 2004
Accepted
12 Mar 2004
First published
05 Apr 2004

Chem. Commun., 2004, 1048-1049

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Ferromagnetic NiII–GdIII interactions in complexes with NiGd, NiGdNi, and NiGdGdNi cores supported by tripodal ligands

T. Yamaguchi, Y. Sunatsuki, M. Kojima, H. Akashi, M. Tsuchimoto, N. Re, S. Osa and N. Matsumoto, Chem. Commun., 2004, 1048 DOI: 10.1039/B401033G

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