Issue 9, 2004
From the journal:

Chemical Communications

Porphyrin ring contraction: a one-pot reaction leading to divalent corroles†

Christophe Jeandon,a   Romain Rupperta  and  Henry J. Callot*a  

* Corresponding authors

a Université Louis Pasteur, UMR CNRS 7123, Faculté de Chimie, 1 rue Blaise Pascal, 67000 Strasbourg, France
E-mail: callot@chimie.u-strasbg.fr

Abstract

Reaction of nickel meso-tetraarylporphyrins with benzoic anhydride and tin tetrachloride, followed by air oxidation under basic conditions, results in ring contraction, yielding divalent corroles.

Graphical abstract: Porphyrin ring contraction: a one-pot reaction leading to divalent corroles

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Article information

DOI
https://doi.org/10.1039/B400812J
Article type
Communication
Submitted
19 Jan 2004
Accepted
11 Mar 2004
First published
02 Apr 2004

Chem. Commun., 2004, 1090-1091

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Porphyrin ring contraction: a one-pot reaction leading to divalent corroles

C. Jeandon, R. Ruppert and H. J. Callot, Chem. Commun., 2004, 1090 DOI: 10.1039/B400812J

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