Issue 4, 2004
From the journal:

Chemical Communications

[VO(H2O)5]H[PMo12O40]-catalyzed nitration of alkanes with nitric acid†

Kazuya Yamaguchi,a   Satoshi Shinachia  and  Noritaka Mizuno*a  

* Corresponding authors

a Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan
E-mail: tmizuno@mail.ecc.u-tokyo.ac.jp
Fax: +81-3-5841-7220
Tel: +81-3-5841-7272

Abstract

[VO(H2O)5]H[PMo12O40], which contains vanadyl counter cations and PMo12O403−, can act as a catalyst for the nitration of various alkanes including alkylbenzenes using nitric acid as a nitrating agent in acetic acid at 356 K.

Graphical abstract: [VO(H2O)5]H[PMo12O40]-catalyzed nitration of alkanes with nitric acid

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Article information

DOI
https://doi.org/10.1039/B314978A
Article type
Communication
Submitted
19 Nov 2003
Accepted
15 Dec 2003
First published
19 Jan 2004

Chem. Commun., 2004, 424-425

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[VO(H2O)5]H[PMo12O40]-catalyzed nitration of alkanes with nitric acid

K. Yamaguchi, S. Shinachi and N. Mizuno, Chem. Commun., 2004, 424 DOI: 10.1039/B314978A

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