Issue 18, 2003
From the journal:

Chemical Communications

An abrupt spin transition based on short S⋯S contacts in a novel Fe(ii) complex whose ligand contains a 1,3-dithiole ring

Kazuyuki Takahashi,a   Tomoko Kawakami,ab   Zhong-ze Gu,a   Yasuaki Einaga,b   Akira Fujishimac  and  Osamu Sato*a  

* Corresponding authors

a Kanagawa Academy of Science and Technology (KAST), KSP Bldg. East 412, 3-2-1 Sakado, Takatsu-ku, Kanagawa 213-0012, Japan
E-mail: sato@fchem.chem.t.u-tokyo.ac.jp

b Department of Chemistry, Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Yokohama 223-8522, Japan

c Department of Applied Chemistry, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan

Abstract

The first preparation of an Fe(II) spin-crossover complex including a 1,3-dithiole ligand is reported. Crystal analyses of both the low- and the high-temperature phases reveal that short S⋯S contacts play a key role in an abrupt spin transition.

Graphical abstract: An abrupt spin transition based on short S⋯S contacts in a novel Fe(ii) complex whose ligand contains a 1,3-dithiole ring

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Article information

DOI
https://doi.org/10.1039/B308070F
Article type
Communication
Submitted
15 Jul 2003
Accepted
08 Aug 2003
First published
19 Aug 2003

Chem. Commun., 2003, 2374-2375

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An abrupt spin transition based on short S⋯S contacts in a novel Fe(II) complex whose ligand contains a 1,3-dithiole ring

K. Takahashi, T. Kawakami, Z. Gu, Y. Einaga, A. Fujishima and O. Sato, Chem. Commun., 2003, 2374 DOI: 10.1039/B308070F

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