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Synthesis and luminescence behaviour of novel heterodecanuclear silver(i)–rhenium(i) alkynyl complexes. X-Ray crystal structures of [Ag6(μ-dppm)4{μ3-C![[triple bond, length as m-dash]](https://www.rsc.org/images/entities/char_e002.gif)
CCC–Re(Me2bpy)(CO)3}4](PF6)2 and [Ag6(μ-dppm)4{μ3-CCCC–Re(Br2phen)(CO)3}4](PF6)2†
Abstract
A novel series of luminescent heterodecanuclear mixed-metal alkynyl complexes, [Ag6(μ-dppm)4{μ3-CCCC–Re(N∧N)(CO)3}4](PF6)2, (N∧N =
tBu2bpy, Me2bpy, phen, Br2phen), have been successfully synthesized; the X-ray crystal structures of [Ag6(μ-dppm)4{μ3-CCCC–Re(Me2bpy)(CO)3}4](PF6)2 and [Ag6(μ-dppm)4{μ3-CCCC–Re(Br2phen)(CO)3}4](PF6)2 have also been determined.
![Graphical abstract: Synthesis and luminescence behaviour of novel heterodecanuclear silver(i)–rhenium(i) alkynyl complexes. X-Ray crystal structures of [Ag6(μ-dppm)4{μ3-C [[triple bond, length as m-dash]] CC [[triple bond, length as m-dash]] C–Re(Me2bpy)(CO)3}4](PF6)2 and [Ag6(μ-dppm)4{μ3-C [[triple bond, length as m-dash]] CC [[triple bond, length as m-dash]] C–Re(Br2phen)(CO)3}4](PF6)2](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=B307479J&imageInfo.ImageIdentifier.Year=2003)
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![[triple bond, length as m-dash]](https://www.rsc.org/images/entities/h2_char_e002.gif)
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