Issue 17, 2003

New monodentate chiral phosphite ligands for asymmetric hydrogenation

Abstract

We report the synthesis of new chiral monodentate phosphite ligands with a biphenyl backbone, the axial chirality of which is introduced early in the synthesis and locked by a chiral alkylenedioxy bridge. We also describe results obtained with these ligands in rhodium-catalysed asymmetric hydrogenation of various substrates.

Graphical abstract: New monodentate chiral phosphite ligands for asymmetric hydrogenation

Article information

Article type
Communication
Submitted
16 Jun 2003
Accepted
14 Jul 2003
First published
22 Jul 2003

Chem. Commun., 2003, 2210-2211

New monodentate chiral phosphite ligands for asymmetric hydrogenation

P. Hannen, H.-Christian Militzer, E. M. Vogl and F. A. Rampf, Chem. Commun., 2003, 2210 DOI: 10.1039/B306793A

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