Issue 18, 2003
From the journal:

Chemical Communications

Template polymerization of columnar architectures based on the salts of a carboxylic acid and 2-amino alcohols: application to the molecular recognition of 2-amino alcohols†

Yasuhiro Ishida,a   Sayaka Amanob  and  Kazuhiko Saigo*ab  

* Corresponding authors

a Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, Hongo, Tokyo 113-8656, Japan
E-mail: saigo@chiral.t.u-tokyo.ac.jp
Fax: (+81) 3 5802 3348
Tel: (+81) 3 5841 7266

b Department of Integrated Biosciences, Graduate School of Frontier Sciences, The University of Tokyo, Bioscience Bldg. 702, Kashiwa, Chiba 277-8562, Japan

Abstract

The salts of trialkoxybenzoic acids and 2-amino alcohols showed a columnar liquid crystalline phase; in the case of the salt of a polymerizable acid and norephedrine, the photopolymerization proceeded efficiently in the liquid crystalline state, and the resultant solid adsorbed 2-amino alcohols size-, regio-, and enantio-selectively.

Graphical abstract: Template polymerization of columnar architectures based on the salts of a carboxylic acid and 2-amino alcohols: application to the molecular recognition of 2-amino alcohols

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Article information

DOI
https://doi.org/10.1039/B305625B
Article type
Communication
Submitted
21 May 2003
Accepted
25 Jul 2003
First published
07 Aug 2003

Chem. Commun., 2003, 2338-2339

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Template polymerization of columnar architectures based on the salts of a carboxylic acid and 2-amino alcohols: application to the molecular recognition of 2-amino alcohols

Y. Ishida, S. Amano and K. Saigo, Chem. Commun., 2003, 2338 DOI: 10.1039/B305625B

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