Issue 16, 2003

Synergetic activation of “silent receptor” sites leading to a new type of inclusion complex: integration of a 64-membered ring comprising K+ and SO42− ions into a molybdenum oxide-based nanoobject

Abstract

The new type of inclusion species [MoVI114MoV32O429(H2O)50(KSO4)16]30− comprising 16 encapsulated K+ and SO42− ions shows an unusual 64-membered {K(SO4)}16 ring integrated into a wheel-shaped type nanocluster host; it is formed by a synergetically induced functional complementarity and represents a text-book example of a very complex non-biological material.

Graphical abstract: Synergetic activation of “silent receptor” sites leading to a new type of inclusion complex: integration of a 64-membered ring comprising K+ and SO42− ions into a molybdenum oxide-based nanoobject

Supplementary files

Article information

Article type
Communication
Submitted
15 May 2003
Accepted
20 Jun 2003
First published
11 Jul 2003

Chem. Commun., 2003, 2000-2001

Synergetic activation of “silent receptor” sites leading to a new type of inclusion complex: integration of a 64-membered ring comprising K+ and SO42− ions into a molybdenum oxide-based nanoobject

A. Müller, L. Toma, H. Bögge, M. Schmidtmann and P. Kögerler, Chem. Commun., 2003, 2000 DOI: 10.1039/B305447K

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