Issue 14, 2003
From the journal:

Chemical Communications

Bis(phosphinimino)methyl derivatives of Ca, Sr and Ba: facile access to heavier alkaline earth organometallic chemistry

Michael S. Hill*a  and  Peter B. Hitchcockb  

* Corresponding authors

a Department of Chemistry, Imperial College London, Exhibition Road, South Kensington, UK
E-mail: mike.hill@imperial.ac.uk
Fax: +44 (0)20 7594 5804
Tel: +44 (0)207 594 5709

b The Chemistry Laboratory, University of Sussex, Falmer, UK

Abstract

A series of mononuclear and arene-soluble bis(phosphinimino)methyl derivatives of the heavier alkaline earth metals, calcium, strontium and barium, have been obtained by straightforward addition of two molar equivalents of [KN(SiMe3)2] to a mixture of [CH2(Ph2P[double bond, length as m-dash]NC6H2-Me3-2,4,6)2] and MI2 (M = Ca, Sr, Ba) in THF.

Graphical abstract: Bis(phosphinimino)methyl derivatives of Ca, Sr and Ba: facile access to heavier alkaline earth organometallic chemistry

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Article information

DOI
https://doi.org/10.1039/B305430F
Article type
Communication
Submitted
15 May 2003
Accepted
02 Jun 2003
First published
18 Jun 2003

Chem. Commun., 2003, 1758-1759

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Bis(phosphinimino)methyl derivatives of Ca, Sr and Ba: facile access to heavier alkaline earth organometallic chemistry

M. S. Hill and P. B. Hitchcock, Chem. Commun., 2003, 1758 DOI: 10.1039/B305430F

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