Issue 16, 2003
From the journal:

Chemical Communications

Homoatomic P → P coordination: A versatile synthetic approach to polyphosphorus dications

Neil Burford,*a   Paul J. Ragogna,a   Robert McDonaldb  and  Michael J. Fergusonb  

* Corresponding authors

a Department of Chemistry, Dalhousie University, Halifax, Nova Scotia, B3H 4J3, Canada
E-mail: Neil.Burford@dal.ca
Fax: (1)902-494-1310
Tel: (1)902-494-3190

b X-ray Crystallography Laboratory, Department of Chemistry, University of Alberta, Edmonton, Alberta, T6G 2G2, Canada
E-mail: Bob.McDonald@ualberta.ca
Fax: (1)780-492-8231
Tel: (1)780-492-2485

Abstract

Polyphosphorus dications have been synthesised and comprehensively characterised as diphosphine (dppe, dmpe and dpph) linked Ar2P+ Lewis acids (Ar = C6H5); this application of unique homoatomic coordination chemistry provides important building blocks for extended systems.

Graphical abstract: Homoatomic P → P coordination: A versatile synthetic approach to polyphosphorus dications

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Article information

DOI
https://doi.org/10.1039/B304984A
Article type
Communication
Submitted
02 May 2003
Accepted
16 Jun 2003
First published
10 Jul 2003

Chem. Commun., 2003, 2066-2067

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Homoatomic P → P coordination: A versatile synthetic approach to polyphosphorus dications

N. Burford, P. J. Ragogna, R. McDonald and M. J. Ferguson, Chem. Commun., 2003, 2066 DOI: 10.1039/B304984A

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