Issue 6, 2003
From the journal:

Chemical Communications

Convergent access to ketones, vinyl esters and vinyl bromides by a tin-free radical addition-intramolecular hydrogen atom transfer†

Gilles Ouvry*a  and  Samir Z. Zarda  

* Corresponding authors

a Laboratoire de Synthèse Organique associé au CNRS, Ecole Polytechnique, 91128 Palaiseau, France
E-mail: zard@poly.polytechnique
Fax: +33(0)169333851
Tel: +33 (0)169334872

Abstract

Xanthate-mediated intermolecular radical addition, hydrogen atom transfer and sulfonyl radical elimination have been efficiently combined in a new convergent synthesis of ketones and substituted olefins.

Graphical abstract: Convergent access to ketones, vinyl esters and vinyl bromides by a tin-free radical addition-intramolecular hydrogen atom transfer

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Article information

DOI
https://doi.org/10.1039/B212841A
Article type
Communication
Submitted
03 Jan 2002
Accepted
12 Feb 2003
First published
21 Feb 2003

Chem. Commun., 2003, 778-779

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Convergent access to ketones, vinyl esters and vinyl bromides by a tin-free radical addition-intramolecular hydrogen atom transfer

G. Ouvry and S. Z. Zard, Chem. Commun., 2003, 778 DOI: 10.1039/B212841A

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