Issue 6, 2003
From the journal:

Chemical Communications

Ruthenium catalyzed regioselective hydrophosphination of propargyl alcohols

François Jérôme,a   Florian Monnier,a   Hania Lawicka,a   Sylvie Dériena  and  Pierre H. Dixneuf*a  

* Corresponding authors

a Institut de Chimie de Rennes, UMR 6509—CNRS—Université de Rennes, Organométalliques et Catalyse, Campus de Beaulieu 35042, Rennes, France
E-mail: pierre.dixneuf@univ-rennes1.fr
Fax: 33 2 23 23 69 39
Tel: 33 2 23 23 62 80

Abstract

Catalytic hydrophosphination of propargyl alcohols by ruthenium complexes RuCl(cod)(C5Me5) and RuCl(PPh3)2(C5Me5) leads to the formation of functionalized vinylphosphines, with linkage of the phosphorus atom to the terminal alkyne carbon, via a ruthenium vinylidene intermediate.

Graphical abstract: Ruthenium catalyzed regioselective hydrophosphination of propargyl alcohols

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Article information

DOI
https://doi.org/10.1039/B212408D
Article type
Communication
Submitted
17 Dec 2002
Accepted
05 Feb 2003
First published
17 Feb 2003

Chem. Commun., 2003, 696-697

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Ruthenium catalyzed regioselective hydrophosphination of propargyl alcohols

F. Jérôme, F. Monnier, H. Lawicka, S. Dérien and P. H. Dixneuf, Chem. Commun., 2003, 696 DOI: 10.1039/B212408D

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