Issue 4, 2003
From the journal:

Chemical Communications

Novel and efficient chiral sulfideoxathiane ligands for palladium-catalyzed asymmetric allylic alkylation†

Yuko Okuyama,a   Hiroto Nakano,*a   Kouichi Takahashi,a   Hiroshi Hongoa  and  Chizuko Kabuto*b  

* Corresponding authors

a Tohoku Pharmaceutical University, 4-4-1 Komatsushima, Aoba-ku, Sendai, Japan
E-mail: hnakano@tohoku-pharm.ac.jp
Fax: 81 22 275 2013
Tel: 81 22 234 4181

b Instrumental Analysis Center for Chemistry, Graduate School of Science, Tohoku University, Aoba, Aramaki, Aoba-ku, Sendai, Japan
E-mail: kabuto@kiki.chem.tohoku.ac.jp

Abstract

Easily prepared, chiral sulfideoxathiane ligands are described which give excellent enantioselectivity (up to 99% ee) in the Pd-catalyzed allylic alkylation of 1,3-diphenyl-2-propenyl acetate with a range of alkyl malonate nucleophiles.

Graphical abstract: Novel and efficient chiral sulfideoxathiane ligands for palladium-catalyzed asymmetric allylic alkylation

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Article information

DOI
https://doi.org/10.1039/B211031H
Article type
Communication
Submitted
08 Nov 2002
Accepted
02 Jan 2003
First published
17 Jan 2003

Chem. Commun., 2003, 524-525

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Novel and efficient chiral sulfideoxathiane ligands for palladium-catalyzed asymmetric allylic alkylation

Y. Okuyama, H. Nakano, K. Takahashi, H. Hongo and C. Kabuto, Chem. Commun., 2003, 524 DOI: 10.1039/B211031H

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