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Issue 3, 2003
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The anionic thia-Fries rearrangement of aryl triflates

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Abstract

Aryl triflates undergo LDA-mediated rearrangement to generate o-hydroxyaryl trifluoromethylsulfones. In some cases, partitioning between rearrangement and aryne generation can be controlled.

Graphical abstract: The anionic thia-Fries rearrangement of aryl triflates

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Publication details

The article was received on 30 Oct 2002, accepted on 17 Dec 2002 and first published on 14 Jan 2003


Article type: Communication
DOI: 10.1039/B210648E
Citation: Chem. Commun., 2003,0, 380-381
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    The anionic thia-Fries rearrangement of aryl triflates

    J. P. H. Charmant, A. M. Dyke and G. C. Lloyd-Jones, Chem. Commun., 2003, 0, 380
    DOI: 10.1039/B210648E

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