Issue 2, 2003

Effects of a nonplanar porphyrin rings on the spin–spin interactions in low-spin ferric porphyrin radical cations

Abstract

Low-spin ferric porphyrin radical cations formed by the oxidation of chloro(meso-tetraalkylporphyrinato)iron(III) followed by the addition of bulky 2-methylimidazole show antiferromagnetic coupling, which is interpreted in terms of the interaction between porphyrin a2u and iron dxy orbitals caused by the S4 ruffling of the porphyrin core.

Graphical abstract: Effects of a nonplanar porphyrin rings on the spin–spin interactions in low-spin ferric porphyrin radical cations

Supplementary files

Article information

Article type
Communication
Submitted
18 Oct 2002
Accepted
29 Nov 2002
First published
12 Dec 2002

Chem. Commun., 2003, 220-221

Effects of a nonplanar porphyrin rings on the spin–spin interactions in low-spin ferric porphyrin radical cations

T. Ikeue, Y. Ohgo and M. Nakamura, Chem. Commun., 2003, 220 DOI: 10.1039/B210229C

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