Issue 1, 2003
From the journal:

Chemical Communications

A chiral metallacyclophane for asymmetric catalysis†

Hua Jiang,a   Aiguo Hua  and  Wenbin Lin*a  

* Corresponding authors

a Department of Chemistry, CB#3290, University of North Carolina, Chapel Hill, NC, USA
E-mail: wlin@unc.edu

Abstract

Chiral metallacyclophanes were self-assembled from cis-(PEt3)2PtCl2 and enantiopure atropisomeric 1,1′-binaphthyl-6,6′-bis(acetylenes) and used in highly enantioselective catalytic diethylzinc additions to aldehydes to afford chiral secondary alcohols.

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Article information

DOI
https://doi.org/10.1039/B208324H
Article type
Communication
Submitted
26 Aug 2002
Accepted
05 Nov 2002
First published
03 Dec 2002

Chem. Commun., 2003, 96-97

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A chiral metallacyclophane for asymmetric catalysis

H. Jiang, A. Hu and W. Lin, Chem. Commun., 2003, 96 DOI: 10.1039/B208324H

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