Issue 24, 2002
From the journal:

Chemical Communications

Conformational landscape surfing induced by off–on π–π stacking in a porphyrin–quinone dyad

Daniel J. Nurco,ab   Kevin M. Smithc  and  Jack Fajera  

a Materials Science Department, Brookhaven National Laboratory, Upton, New York, USA
E-mail: fajerj@bnl.gov

b Department of Chemistry, University of California, Davis, California, USA
E-mail: djnurco@ucdavis.edu

c Department of Chemistry, Louisiana State University, Baton Rouge, Louisiana, USA
E-mail: kmsmith@lsu.edu

Abstract

A covalently linked porphyrin–quinone dyad crystallizes with two orientations of the quinone, extended away from (off) and cofacial with the porphyrin macrocycle (on), which induce different conformations of the macrocycle and model the recently proposed structural effect of a nearby residue on the heme prosthetic group of a nitric oxide synthase.

Graphical abstract: Conformational landscape surfing induced by off–on π–π stacking in a porphyrin–quinone dyad

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B209238G
Article type
Communication
Submitted
20 Sep 2002
Accepted
29 Oct 2002
First published
18 Nov 2002

Chem. Commun., 2002, 2982-2983

Permissions

Request permissions

Conformational landscape surfing induced by off–on π–π stacking in a porphyrin–quinone dyad

D. J. Nurco, K. M. Smith and J. Fajer, Chem. Commun., 2002, 2982 DOI: 10.1039/B209238G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements