Issue 23, 2002
From the journal:

Chemical Communications

NMR characterisation of unstable solvent and dihydride complexes generated at low temperature by in-situ UV irradiation†

Cyril Godard,a   Philip Callaghan,a   Jenny L. Cunningham,a   Simon B. Duckett,*a   Joost A. B. Lohmanb  and  Robin N. Perutza  

* Corresponding authors

a Department of Chemistry, University of York, Heslington, York, UK
E-mail: sbd3@york.ac.uk

b Bruker BioSpin, Banner Lane, Coventry, UK

Abstract

Low temperature in-situ UV irradiation of toluene solutions containing bis(alkene)rhodium complexes and parahydrogen in conjunction with NMR monitoring enables the characterisation of unstable η2-solvent complexes and dihydrogen activation products.

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Article information

DOI
https://doi.org/10.1039/B208007A
Article type
Communication
Submitted
15 Aug 2002
Accepted
08 Oct 2002
First published
28 Oct 2002

Chem. Commun., 2002, 2836-2837

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NMR characterisation of unstable solvent and dihydride complexes generated at low temperature by in-situ UV irradiation

C. Godard, P. Callaghan, J. L. Cunningham, S. B. Duckett, J. A. B. Lohman and R. N. Perutz, Chem. Commun., 2002, 2836 DOI: 10.1039/B208007A

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