Issue 18, 2002

Reductive decomplexation of π-allyltricarbonyliron lactone complexes; a new route to stereo-defined 1,7-diols and 2,3-diene-1,7-diols

Abstract

Treatment of π-allyltricarbonyliron lactone complexes bearing an adjacent leaving group, with lithium naphthalenide causes decomplexation to acyclic dienols in excellent yield and without any scrambling of the allylic centre.

Graphical abstract: Reductive decomplexation of π-allyltricarbonyliron lactone complexes; a new route to stereo-defined 1,7-diols and 2,3-diene-1,7-diols

Supplementary files

Article information

Article type
Communication
Submitted
02 Jul 2002
Accepted
08 Aug 2002
First published
22 Aug 2002

Chem. Commun., 2002, 2130-2131

Reductive decomplexation of π-allyltricarbonyliron lactone complexes; a new route to stereo-defined 1,7-diols and 2,3-diene-1,7-diols

C. J. Hollowood and S. V. Ley, Chem. Commun., 2002, 2130 DOI: 10.1039/B206406P

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements