Issue 16, 2002
From the journal:

Chemical Communications

Tandem isomerization/Claisen transformation of allyl homoallyl and diallyl ethers into γ,δ-unsaturated aldehydes with a new three component catalyst Ru3(CO)12/imidazolinium salt/Cs2CO3

Jérôme Le Nôtre,a   Luc Brissieux,a   David Sémeril,a   Christian Bruneaua  and  Pierre H. Dixneuf*a  

* Corresponding authors

a Institut de Chimie de Rennes, UMR 6509 CNRS-Université de Rennes, Organométalliques et Catalyse, Campus de Beaulieu, Rennes, France
E-mail: dixneuf@univ-rennes1.fr

Abstract

The three component catalyst Ru3(CO)12/1,3-bis(2,6-diisopropylphenyl)imidazolinium chloride/Cs2CO3 (molar ratio 1∶3∶6) successively promotes both allyl to vinyl isomerization and Claisen rearrangement from allyl homoallyl and diallyl ethers to selectively afford γ,δ-unsaturated aldehydes.

Graphical abstract: Tandem isomerization/Claisen transformation of allyl homoallyl and diallyl ethers into γ,δ-unsaturated aldehydes with a new three component catalyst Ru3(CO)12/imidazolinium salt/Cs2CO3

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/B205805G
Article type
Communication
Submitted
14 Jun 2002
Accepted
08 Jul 2002
First published
17 Jul 2002

Chem. Commun., 2002, 1772-1773

Permissions

Request permissions

Tandem isomerization/Claisen transformation of allyl homoallyl and diallyl ethers into γ,δ-unsaturated aldehydes with a new three component catalyst Ru3(CO)12/imidazolinium salt/Cs2CO3

J. Le Nôtre, L. Brissieux, D. Sémeril, C. Bruneau and P. H. Dixneuf, Chem. Commun., 2002, 1772 DOI: 10.1039/B205805G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements