Issue 17, 2002
From the journal:

Chemical Communications

(η5-Cyclopentadienyl)(η4-di- and tetra-phosphorylcyclobutadiene)cobalt(i): Synthesis, structure, and formation of 1-D coordination polymer†

Shigeru Sasaki,*a   Yoshihiro Tanabea  and  Masaaki Yoshifuji*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Tohoku University, Aoba, Sendai 980-8578, Japan
E-mail: yoshifj@mail.cc.tohoku.ac.jp
Fax: +81 22 217 6562
Tel: +81 22 217 6558

Abstract

(η5-Cyclopentadienyl)(η4-di- and tetra-phosphorylcyclobutadiene)cobalt(I) complexes were synthesized by the reaction of mono- and diphosphorylacetylenes with CpCo(CO)2, respectively. The tetraphosphoryl derivative has proved to work as a bis-bidentate ligand affording a one-dimensional coordination polymer with Ce(III).

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Article information

DOI
https://doi.org/10.1039/B204779A
Article type
Communication
Submitted
17 May 2002
Accepted
11 Jul 2002
First published
25 Jul 2002

Chem. Commun., 2002, 1876-1877

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(η5-Cyclopentadienyl)(η4-di- and tetra-phosphorylcyclobutadiene)cobalt(I): Synthesis, structure, and formation of 1-D coordination polymer

S. Sasaki, Y. Tanabe and M. Yoshifuji, Chem. Commun., 2002, 1876 DOI: 10.1039/B204779A

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