2-D soft ferromagnet based on [WV(CN)8]3− and CuII with a Tc of 34 K

Robert Podgajny; Tomasz Korzeniak; Maria Balanda; Tadeusz Wasiutynski; William Errington; Terence J. Kemp; Nathaniel W. Alcock; Barbara Sieklucka

doi:10.1039/B202810G

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

2-D soft ferromagnet based on [W^V(CN)₈]³⁻ and Cu^II with a T_c of 34 K†

Robert Podgajny,^a Tomasz Korzeniak,^a Maria Balanda,^b Tadeusz Wasiutynski,^b William Errington,^c Terence J. Kemp,^c Nathaniel W. Alcock^c and Barbara Sieklucka*^a

Author affiliations

* Corresponding authors

^a Faculty of Chemistry, Jagiellonian University, Ingardena 3, Kraków, Poland
E-mail: siekluck@chemia.uj.edu.pl

^b H. Niewodniczanski Institute of Nuclear Physics, Radzikowskiego 152, Kraków, Poland

^c Department of Chemistry, University of Warwick, Coventry, UK

Abstract

Self-assembly of [Cu(tetren)]²⁺ (tetren = tetraethylenepentamine) and [W(CN)₈]³⁻ in acidic aqueous solution yields the double-layered square grid cyanide-bridged polymer of {(tetrenH₅)_0.8Cu^II₄[W^V(CN)₈]₄·7.2H₂O}_n with Cu(II) centres of square pyramidal geometry coordinatively saturated solely by CN bridges supplied by five [W(CN)₈]³⁻ ions; it exhibits soft ferromagnetic behaviour with an ordering temperature T_c of 34 K.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/B202810G
Article type: Communication
Submitted: 19 Mar 2002
Accepted: 15 Apr 2002
First published: 23 Apr 2002

Download Citation

Chem. Commun., 2002, 1138-1139

Permissions

Request permissions

2-D soft ferromagnet based on [W^V(CN)₈]³⁻ and Cu^II with a T_c of 34 K

R. Podgajny, T. Korzeniak, M. Balanda, T. Wasiutynski, W. Errington, T. J. Kemp, N. W. Alcock and B. Sieklucka, Chem. Commun., 2002, 1138 DOI: 10.1039/B202810G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications