Issue 8, 2002

Efficient amination of sulfides with a ketomalonate-derived oxaziridine: application to [2,3]-sigmatropic rearrangements of allylic sulfimides

Abstract

A novel N-Boc-oxaziridine is reported, derived from diethyl ketomalonate, which effects efficient amination of sulfides to sulfimides. The reagent is applied to the [2,3]-sigmatropic rearrangement of allylic sulfimides.

Graphical abstract: Efficient amination of sulfides with a ketomalonate-derived oxaziridine: application to [2,3]-sigmatropic rearrangements of allylic sulfimides

Supplementary files

Article information

Article type
Communication
Submitted
19 Feb 2002
Accepted
13 Mar 2002
First published
26 Mar 2002

Chem. Commun., 2002, 904-905

Efficient amination of sulfides with a ketomalonate-derived oxaziridine: application to [2,3]-sigmatropic rearrangements of allylic sulfimides

A. Armstrong and R. S. Cooke, Chem. Commun., 2002, 904 DOI: 10.1039/B201791A

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