Issue 9, 2002
From the journal:

Chemical Communications

Stepwise, ring-closure synthesis and characterization of a homoleptic palladium(ii)-pyrazolato cyclic trimer

Peter Baran,a   Cruz M. Marrero,a   Soribel Péreza  and  Raphael G. Raptis*a  

* Corresponding authors

a Department of Chemistry, University of Puerto Rico, P. O. Box 23346, San Juan, USA
E-mail: raphael@adam.uprr.pr

Abstract

A triangular homoleptic complex, [Pd(μ-3-Ph-pz)2]3, is prepared by the stepwise formation of an open-chain trimer and subsequent ring-closure; D3 molecular symmetry results from the one-directional arrangement of the unsymmetrically substituted pyrazolato ligands; the palladium atoms are held in close proximity, with Pd–Pd distances of 2.997(1)–3.087(1) Å.

Graphical abstract: Stepwise, ring-closure synthesis and characterization of a homoleptic palladium(ii)-pyrazolato cyclic trimer

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Article information

DOI
https://doi.org/10.1039/B201301K
Article type
Communication
Submitted
04 Feb 2002
Accepted
19 Mar 2002
First published
08 Apr 2002

Chem. Commun., 2002, 1012-1013

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Stepwise, ring-closure synthesis and characterization of a homoleptic palladium(II)-pyrazolato cyclic trimer

P. Baran, C. M. Marrero, S. Pérez and R. G. Raptis, Chem. Commun., 2002, 1012 DOI: 10.1039/B201301K

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