Issue 8, 2002
From the journal:

Chemical Communications

Albumin-controlled stereoselective reduction of 1,3-diketones to anti-diols†

Fabio Benedetti,*a   Federico Berti,*a   Ivan Donatia  and  Massimo Fregonesea  

* Corresponding authors

a Dipartimento di Scienze Chimiche, Università di Trieste, Via Giorgieri 1, Trieste, Italy
E-mail: berti@dsch.univ.trieste.it
Fax: 39 040 6763903
Tel: 39 040 6763920

Abstract

An unprecedented combination of high chemo- and stereoselectivity in the NaBH4 reduction of 1∶1 complexes between albumin and aromatic 1,3-diketones results in the formation of anti 1,3-diols with de up to 96%.

Graphical abstract: Albumin-controlled stereoselective reduction of 1,3-diketones to anti-diols

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Article information

DOI
https://doi.org/10.1039/B200474G
Article type
Communication
Submitted
15 Jan 2002
Accepted
05 Mar 2002
First published
15 Mar 2002

Chem. Commun., 2002, 828-829

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Albumin-controlled stereoselective reduction of 1,3-diketones to anti-diols

F. Benedetti, F. Berti, I. Donati and M. Fregonese, Chem. Commun., 2002, 828 DOI: 10.1039/B200474G

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