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Issue 8, 2002
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Organometallic chemistry of carbaporphyrinoids: synthesis and characterization of nickel(II) and palladium(II) azuliporphyrins

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Abstract

Brief treatment of azuliporphyrins 5 with nickel(II) or palladium(II) acetate in refluxing DMF afforded excellent yields of the related chelates; these novel organometallic compounds retain cross-conjugated borderline aromatic structures as judged by UV-Vis and NMR spectroscopy, and X-ray crystallography.

Graphical abstract: Organometallic chemistry of carbaporphyrinoids: synthesis and characterization of nickel(ii) and palladium(ii) azuliporphyrins

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The article was received on 27 Dec 2001, accepted on 12 Mar 2002 and first published on 25 Mar 2002


Article type: Communication
DOI: 10.1039/B200131B
Citation: Chem. Commun., 2002, 894-895
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    Organometallic chemistry of carbaporphyrinoids: synthesis and characterization of nickel(II) and palladium(II) azuliporphyrins

    S. R. Graham, G. M. Ferrence and T. D. Lash, Chem. Commun., 2002, 894
    DOI: 10.1039/B200131B

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