Issue 4, 2002
From the journal:

Chemical Communications

Evidence for through-framework electron transfer in intrazeolite photochemistry. Case of Ru(bpy)32+ and methylviologen in novel delaminated ITQ-2 zeolite

Avelino Corma,*a   Vicente Fornés,a   María S. Galletero,a   Hermenegildo García*a  and  J. C. Scaiano*b  

* Corresponding authors

a Instituto de Tecnología Química CSIC-UPV, Universidad Politécnica de Valencia, Avda de los Naranjos s/n, Valencia, Spain
E-mail: hgarcia@qim.upv.es

b Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, Canada

Abstract

A sample of novel delaminated zeolite ITQ-2 containing Ru(bpy)32+ on the external cups and MV2+ included in the independent and not connected channels has been prepared; emission and time-resolved laser flash photolysis has shown unambigously that photoinduced electron transfer from Ru(bpy)32+ to MV2+ occurs through the zeolite framework.

Graphical abstract: Evidence for through-framework electron transfer in intrazeolite photochemistry. Case of Ru(bpy)32+ and methylviologen in novel delaminated ITQ-2 zeolite

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Article information

DOI
https://doi.org/10.1039/B110440C
Article type
Communication
Submitted
15 Nov 2001
Accepted
03 Jan 2002
First published
05 Feb 2002

Chem. Commun., 2002, 334-335

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Evidence for through-framework electron transfer in intrazeolite photochemistry. Case of Ru(bpy)32+ and methylviologen in novel delaminated ITQ-2 zeolite

A. Corma, V. Fornés, M. S. Galletero, H. García and J. C. Scaiano, Chem. Commun., 2002, 334 DOI: 10.1039/B110440C

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