Formation and reactivity of a cobalt(ii) hydroperoxide intermediate
Abstract
Reaction of Tpt-Bu,MeCo–H with O2 proceeds via a spectroscopically observable hydroperoxide whose reactivity in solution and in the solid state differ dramatically.
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* Corresponding authors
a
Department of Chemistry and Biochemistry, Center for Catalytic Science and Technology, University of Delaware, Newark, DE, USA.
E-mail:
theopold@udel.edu
Reaction of Tpt-Bu,MeCo–H with O2 proceeds via a spectroscopically observable hydroperoxide whose reactivity in solution and in the solid state differ dramatically.
Formation and reactivity of a cobalt(II) hydroperoxide intermediate
S. Thyagarajan, C. D. Incarvito, A. L. Rheingold and K. H. Theopold, Chem. Commun., 2001, 2198 DOI: 10.1039/B107080K
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